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You would look at the periodic table to find an atom that you could add 5 to its number of protons that would give you a sum close to the atomic mass given for that element.
All elements from atomic numbers 1 () to 118 () have been discovered or synthesized, with the most recent additions (, , , and ) being confirmed by the (IUPAC) on December 30, 2015 and officially named on November 28, 2016: they complete the first seven rows of the periodic table.
The first 94 elements exist naturally, although some are found only in trace amounts and were synthesized in laboratories before being found in nature.
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Most of his predictions were proved correct when the elements in question were subsequently discovered.